Food Additive Sodium Hexametaphosphate - High-Quality Water Softener for Food Applications
Sodium Hexametaphosphate (NaPO₃)₆, a high-purity polyphosphate compound, is a versatile food additive acclaimed for its superior water-softening, sequestering, and emulsifying capabilities. With ≥98% purity (compliant with FCC/USP standards), this white granular powder effectively binds calcium, magnesium, and heavy metal ions, preventing scale formation, improving texture, and extending shelf life in processed meats, dairy, beverages, and canned goods. Its robust ion-chelating capacity and pH stability make SHMP indispensable for manufacturers prioritizing process efficiency, product consistency, and compliance with global food safety regulations.
Functional Benefits
1. Water Softening & Ion Chelation
- Metal sequestration: Binds 1.5–2.0 mmol Ca²⁺/g, preventing scale in processing equipment and beverage lines
- pH stabilization: Maintains solution pH 6.5–8.0 to inhibit protein denaturation in dairy products
- Heavy metal mitigation: Reduces lead/copper contamination in canned foods by 50% (0.05–0.1% dosage)
2. Texture & Emulsion Optimization
- Meat hydration: Enhances water-holding capacity by 15–20% in injected poultry and brined meats
- Dairy stabilization: Prevents casein coagulation in UHT milk (0.01–0.03% usage)
- Seafood protection: Inhibits struvite crystal formation in canned tuna (0.05–0.15% w/w)
3. Preservation & Shelf-Life Extension
- Microbial control: Disrupts bacterial cell membranes via calcium chelation (0.1% reduces Listeria by 30%)
- Antioxidant synergy: Enhances ascorbic acid efficacy by 40% in fruit preserves
- Color retention: Prevents enzymatic browning in peeled potatoes (1–2% dip solution)
4. Process Efficiency
- Clean-in-place (CIP) systems: Reduces detergent usage by 25% via pre-treatment scale inhibition
- Beverage clarification: Removes tannins and proteins in juices/beers (0.005–0.02% filtration aid)
- Frying oil stability: Extends fryer oil lifespan by 15% through metal ion scavenging
Technical Specifications
- Purity: ≥98% (as NaPO₃)₆, titrimetric analysis
- Appearance: White free-flowing granules (200–500 μm particle size)
- Solubility: 20g/100mL in water (25°C); pH 6.0–7.5 (1% solution)
- Phosphate content: 68–71% (as P₂O₅)
- Heavy metals: Pb <1 ppm, As <0.5 ppm (ICP-OES)
- Fluoride: ≤10 ppm (ion-selective electrode)
- Microbial safety: TPC <1,000 CFU/g; pathogens absent per 25g
Advanced Food Applications
1. Meat & Poultry Processing
- Brining solutions: 0.1–0.3% in poultry injections improves yield by 8–12%
- Cured meats: 0.05–0.1% maintains nitrite stability and pink coloration
- Restructured products: 0.5–1% enhances binding in low-fat sausage formulations
2. Seafood & Aquaculture
- Shrimp processing: 2–4% dip prevents blackspot formation during freezing
- Surimi production: 0.2–0.5% increases gel strength to ≥700g/cm²
- Fish glazing: 5–8% solution reduces freezer burn by 60%
3. Dairy & Alternatives
- Processed cheese: 0.3–0.6% prevents oil separation and improves sliceability
- Plant-based milk: 0.01–0.05% stabilizes calcium fortification in almond/oat bases
- Yogurt: 0.02–0.04% inhibits syneresis during refrigerated storage
4. Beverage Production
- Juice clarification: 0.005–0.01% removes haze-active proteins in apple/citrus juices
- Soft drinks: 0.02–0.05% prevents flavor degradation by chelation of trace metals
- Brewing: 0.001–0.005% reduces oxalate scaling in fermentation tanks
5. Bakery & Prepared Foods
- Dough conditioning: 0.05–0.1% improves gluten elasticity in noodles/pastries
- Canned vegetables: 0.1–0.2% maintains firmness in peas/carrots during retort processing
- Batter coatings: 0.3–0.6% enhances adhesion and crispiness in fried foods
Quality Assurance
- Manufactured under FSSC 22000 and ISO 9001 frameworks
- HACCP-monitored polymerization process (thermal phosphate conversion)
- 24-month shelf life in moisture-resistant, UV-blocking packaging
- Allergen-free production (BRCGS Grade AA facility)
- Blockchain-enabled traceability from raw phosphate sourcing
Sustainable Production
- Phosphorus efficiency: 94% utilization via closed-loop calcination reactors
- Carbon footprint: 0.6 kg CO₂eq/kg (25% lower vs. traditional methods)
- Water stewardship: 90% process water recycled via nanofiltration
- Byproduct valorization: Residual sodium oxides converted to detergents
Operational Guidelines
Optimal Usage Protocols
- Meat brines: Pre-dissolve in chilled water (≤10°C) to prevent hydrolysis
- Beverage systems: Inject post-filtration to avoid interaction with clarifying agents
- Thermal stability: Withstands 200°C/392°F for 15 minutes (e.g., baking/frying)
Synergistic Formulations
- With STPP: 1:1 ratio of SHMP:Sodium Tripolyphosphate enhances calcium chelation
- Citric acid: 0.1% SHMP + 0.05% citrate boosts antioxidant activity in fruits
- Carrageenan: 0.3% SHMP + 0.1% carrageenan improves gel strength in plant-based meats
Regulatory Compliance
- FDA 21 CFR 182.6769 (GRAS)
- EU Regulation (EC) No 1333/2008 (E452i)
- CODEX STAN 192-1995 (INS 452i)
- Halal (JAKIM) & Kosher (OU) certified
Food Additive Sodium Hexametaphosphate sets the industry benchmark for water softening and multifunctional food processing. Its unmatched ion-chelating power and thermal resilience enable manufacturers to enhance product quality, reduce waste, and optimize production workflows. With ultra-low heavy metal specifications and eco-conscious manufacturing practices, SHMP empowers global food brands to meet stringent safety standards while addressing consumer demand for clean-label, sustainable ingredients.
Name | Sodium hexametaphosphate |
Synonyms | Metaphosphoric acid, hexasodium salt Hexasodium metaphosphate Glassy sodium Graham's Salt, Sodium Polymetaphosphate Sodium phosphate(Na6(PO3)6) SHMP Sodium Hexameta phosphate sodium henamephosphate hexasodium cyclohexaphosphoxane-2,4,6,8,10,12-hexolate 2,4,6,8,10,12-hexaoxide Sodium Hexametapho |
CAS | 10124-56-8 |
EINECS | 233-343-1 |
InChI |
InChI=1/6Na.H6O18P6/c;;;;;;1-19(2)13-20(3,4)15-22(7,8)17-24(11,12)18-23(9,10)16-21(5,6)14-19/h;;;;;;(H,1,2)(H,3,4)(H,5,6)(H,7,8)(H,9,10)(H,11,12)/q6*+1;/p- 6 |
Molecular Formula | (NaPO3)6 |
Molar Mass | 611.77 |
Physical and Chemical Properties | Properties of colorless transparent glass flake or white granular crystals. melting point 616 (decomposition) relative density 2.484(20) solubility soluble in water, insoluble in organic solvents. |
Use |
Used as water softener, detergent, preservative, cement hardening agent, fiber and bleaching and dyeing cleaning agent, also used in medicine, food oil, printing and dyeing, tanning, paper making, etc. |



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